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The Antoine equation has poor accuracy with any single parameter set when used from a compound's melting level to its essential temperature. Generally, temperature ranges are chosen to maintain the equation's accuracy of some up to 8-10 percent. For many unstable substances, a number of completely different sets of parameters can be found and used for different temperature ranges. Sublimations and vaporizations of the same substance have separate sets of Antoine coefficients, as do components in mixtures.

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